向景 

职称:教授

博导/硕导:博士生导师

学科专业:应用化学

研究方向:激发态反应活性、磁性材料、光学材料

联系方式:xiangjing@yangtzeu.edu.cn

博士,教授,博士生导师,2011年2月毕业于香港城市大学生物与化学系,2010年9月—2012年2月在香港城市大学从事研究员(Research Fellow)工作,现任教于化学与环境工程学院。2013年入选湖北省“***”计划“***”;2016年入选香港‘求搓学者’;2017年湖北省‘***’;2019年入选为长江大学‘长江人才计划’杰出人才。申请人目前在nature子刊《Communications Chemistry.》、RSC旗舰杂志《Chem. Sci.》以及《Carbohydrate Polymers》、《Chem. Commun.》、《Chem. Eur. J》、《Inorg. Chem.》、《Inorg. Chem. Front.》、《Dalton Trans.》、《Organometallics》、《RSC Advances》、《Frontier in chemistry》、《Eur. J. Inorg. Chem.》、《Polyhedron》等共发表SCI收录文章70多份,其中有6份论文被nature index索引。主要的研究方向在与生物体系中酶的结构或功能相似的模型配合物、含顺磁Ru ^III/Os ^III的异核配合物的合成及磁性研究、Ru ^II/Os ^II/Cu ^I二亚胺配合物的合成及光物理化学性质研究、可见光驱动的有机底物的催化氮化反应等研究领域有多年的研究经验。

个人简历

●1999.09—2003.07 长江大学,高分子材料,学士

●2003.09—2006.07 汕头大学,应用化学,硕士

●2007.09—2011.03 香港城市大学,应用化学,博士

●2010.07—2012.03香港城市大学,应用化学,Research Fellow

●2012.03—2019.01长江大学,副教授

●2019.01—至今    长江大学,教授

●2020.01—2020.12 香港大学,高级访问学者

主要研究项目

●国家自然科学青年项目(21201023):含氰根、氰氨根、叠氮酸根和胍的顺磁的钌、锇的配合物构筑的新型分子基磁性材料,合同经费23万,2013.1-2015.12,主持

●国家自然科学基金面上项目(21771026):含配位胍及衍生物的合成与反应活性研究:一种新型的一氧化氮(NO),合同经费65万,2018.1-2021.12,主持

●湖北省自然科学基金项目(‘***’项目)(2018CFA047):新型的可控的NO释放药物的合成与性能研究,合同经费20万,2018.1-2020.12,主持

代表性成果

学术论文

1. Jing Xiang, * Min Peng, Yi Pan, Li-Juan Luo, Shun-Cheung Cheng, Xin-Xin Jin, Shek-Man Yiu, Wai-Lun Man, Chi-Chiu Ko, Kai-Chung Lau, and Tai-Chu Lau*,Visible Light-Induced Oxidative N-dealkylation of Alkylamines by a Luminescent Osmium(VI) Nitrido Complex, Chem. Sci. 2021, 12,14494.

2. Jing Xiang,* Jiang Zhu, Miaomiao Zhou, Lu-Lu Liu, Li-Xin Wang, Min Peng, Bi-Shun Hou, Shek-Man Yiu, Wai-Pong To, Chi-Ming Che,* Kai-Chung Lau,* and Tai-Chu Lau*,Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide by a luminescent Os(VI) cyanonitrido complex, Chem. Commun., 2022,58, 7988-7991.

3. Min Peng, Xiao-Fan Wu, Li-Xin Wang, Si-Huai Chen, Jing Xiang,* Xin-Xin Jin, Shek-Man Yiu, Bing-Wu Wang,* Song Gao,* Tai-Chu Lau*, Slow Magnetic Relaxation in High-Coordinate Co(II) and Fe(II) Compounds bearing Neutral Tetradentate Ligands, Dalton Trans., 2021, 50, 15327.

4. Qian-Qian Su, Qiong Yuan, Xiao-Fan Wu, Si-Huai Chen,Jing Xiang, * Xin-Xin Jin, Li-Xin Wang, Bing-Wu Wang, Song Gao*and Tai-Chu Lau*, Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(II) and Fe(III) compounds, Chem. Commun., 2021, 57, 781-784.

5. Li-Xin Wang, Jing Xiang, Chuan-Hua Li, Chi-Fai Leung* and Jing Xiang*, Recent Advances on the Applications of Luminescent Pb ²⁺-Containing Metal–Organic Frameworks in White-Light Emission and Sensing, Frontier in chemistry, 2021, 9, 636431. (MINI REVIEW)

6. Xu Zhang, Lanxiang Dai, Pengfei Li, Ting Wang, Liting Qin, Jing Xiang*, Huilin Chang, Characterization of hydrophobic interaction of galactomannan in aqueous solutions using fluorescence-based technique, Carbohydrate Polymers, 2021267, 118183.

7. Qian-Qian Su, Kun Fan, Xin-Da Huang, Jing Xiang,*Shun-Cheung Cheng, Chi-Chiu Ko, Li-Min Zheng,* MohamedallyKurmood and Tai-Chu Lau*, Field-induced slow magnetic relaxation in low spin S = 1/2 mononuclear osmium(V) complexes, Dalton Trans., 2020, 49, 4084–4092.

8. Li-Juan Luo, Qian-Qian Su, Shun-Cheung Cheng,Jing Xiang,* Wai-Lun Man, Wen-Ming Shu,Ming-Hua Zeng, Shek-Man Yiu, Chi-Chiu Ko,* and Tai-Chu Lau*Tunable Luminescent Properties of TricyanoosmiumNitrido Complexes Bearing a Chelating O^N Ligand, Inorg. Chem.2020, 59, 4406−4413.

9. Xin-Xin Jin, Tian Li, Dong-Po Shi, Li-Juan Luo, Qian-Qian Su,Jing Xiang, * Hai-Bing Xu, Chi-Fai Leung and Ming-Hua Zeng, Luminescent phosphine copper(I) complexes with various functionalized bipyridine ligands: synthesis, structures, photophysics and computational study, New J. Chem., 2020, 44, 13393—13400.

10. Jing Xiang*, Xin-Xin Jin, Qian-Qian Su, Shun-Cheung Cheng, Chi-Chiu Ko,* Wai-Lun Man, MinyingXue, Liangliang Wu, Chi-Ming Che,* Tai-Chu Lau,*Photochemical nitrogenation of alkanes and arenesby a strongly luminescent osmium(VI) nitridecomplex, Communications Chemistry, 2019,2, 40.

11. Pui-Yu Ho, Shun-Cheung Cheng, Shek-Man Yiu, Vonika Ka-Man Au,Jing Xiang,*Chi-Fai Leung*and Chi-Chiu Ko*The Important Role of Coordination Geometry on Photophysical Properties of Blue-green Emitting Ruthenium(II) Diisocyano Complexes Bearing 2-Benzoxazol-2-ylphenolate, Inorg. Chem.2019, 58, 11372−11381.

12. Jing Xiang, ^*Qian-Qian Su, Li-Juan Luo, and Tai-Chu Lau ^* Synthesis and Reactivity of an Osmium(III) Aminoguanidine Complex, Dalton Trans., 2019, 48, 11404.

13. Jing Xiang, * Shun-Cheung Cheng, Xin-Xin Jin, Qian-Qian Su,Xin Zhou,Wing-Kin Chu, Chi-Fai Leung and Chi-Chiu Ko,Polynuclear Cu(I) and Ag(I) phosphine complexescontaining multi-dentate polytopic ligands:syntheses, crystal structures andphotoluminescence properties, Dalton Trans., 2019, 48, 741.

14. Qian-Qian Su, Kun Fan, Xin-Xin Jin, Xin-Da Huang, Shun-Cheung Cheng, Li-Juan Luo, Yao-Jie Li, Jing Xiang, ^*Chi-Chiu Ko,Li-Min Zheng,Tai-Chu Lau,Syntheses, Crystal Structures and Magnetic Properties of a Series of Luminescent Lanthanide Complexes Containing Neutral Tetradentate Phenanthroline-amide Ligands. Inorg. Chem. Front.2019, 6,1442.

15. Xin-Xin Jin, Xiao-Xiang Chen, Jing Xiang,* Yun-Zhou Chen, Li-Hui Jia, Bing-Wu Wang,* Shun-Cheung Cheng, Xin Zhou, Chi-Fai Leung,* and Song Gao,*Slow Magnetic Relaxation in a Series of Mononuclear 8‑CoordinateFe(II) and Co(II) Complexes, Inorg. Chem.2018, 57, 3761−3774.

16. C.-F. Leung, S.-C. Cheng, Y. Yang,J. Xiang, S.-M. Yiu,C.-C. Ko and T.-C. LauEfficient photocatalytic water reduction by acobalt(II) tripodal iminopyridine complex Catal. Sci. Technol., 2018,8, 307.

17. J.Xiang,*J.-J. Liu, X.-X. Chen, L.-H. Jia,F. Yu, B.-W. Wang,S. Gao, T.-C. Lau, Slow magnetic relaxation in a mononuclear8-coordinate Fe(II) complex, Chem. Commun., 2017, 53, 1474-1477.

18. J.Xiang,*Qian Wang, Shek-Man Yiu, Tai-Chu Lau, Dual Pathways in the Oxidation of an Osmium(III) GuanidineComplex. Formation of Osmium(VI) Nitrido and Osmium NitrosylComplex, Inorg. Chem.2017, 56, 2022−2028.

19. L.-L. Hu, C. Shen, W.-K. Chu,J.Xiang,* Fei Yu, Ge Xiang, Yan Nie,C.-L. Kwok, C.-F. Leung, C.-C. Ko, Synthesis, structures and photophysical properties of Cu(I) phosphinecomplexes with various diimine ligands, Polyhedron2017, 127, 203–211.

20. J. Xiang, Q. Wang, S.-M.Yiu, W.-L. Man, H.-K.Kwong, T.-C. Lau, Aerobic Oxidation of an Osmium(III) N‑Hydroxyguanidine ComplexTo Give Nitric Oxide, Inorg. Chem. 2016, 55, 5056−5061.

21. J.Xiang,*C. Shen, S.-C. Cheng, F. Yu, W.-K. Chu,H. Feng, S.-M.Yiu, C.-C. Ko, C.-F. Leung,Luminescence behaviour of Pb2+-basedcage-containing and channel-containing porouscoordination polymers, Dalton Trans., 2016, 45, 16134–16138.

22. F. Yu, W.-K. Chu, C. Shen, Y. Luo, J. Xiang,* S.-Q. Chen,C.-C. Ko, T.-C. Lau, Luminescent Carbonyl Hydrido Ruthenium(II) DiimineCoordination Compounds: Structural, Photophysical, andElectrochemical Properties, Eur. J. Inorg. Chem.2016, 3892–3899.

23. F. Yu, C. Shen, T. Zheng, W.-K. Chu,J.Xiang,* Y. Luo,C.-C. Ko, Z.-Q. Guo, T.-C. Lau, Acid–Base Behaviour in the Absorption and Emission Spectra ofRuthenium(II) Complexes with Hydroxy-Substituted Bipyridineand Phenanthroline Ligands, Eur. J. Inorg. Chem. 2016, 3641–3648.

24. Chang Shen, Fei Yu, Wing-Kin Chu, Jing Xiang,* Peng Tan, Ya Luo, Hua Feng, Zheng-Qing Guo,* Chi-Fai Leung* and Tai-Chu Lau, Synthesis, structures and photophysical properties of luminescent cyanoruthenate(II) complexes with hydroxylated bipyridine and phenanthroline ligands, RSC Adv.,2016, 6,87389–87399.

25. Jing Xiang,* Li-Hui Jia, Hui-Sheng Wang, Shie-Ming Peng, Song Gao,* and Tai-Chu Lau*, Synthesis, Crystal Structures, and Magnetic Properties of HeterodimetallicRu ^III–3d Coordination Compounds Based on a Meridional Tricyanoruthenium(III) Building Block, Eur. J. Inorg. Chem. 2015, 1065–1073.

26. Zheng-nengJin , Hua-jiang Jiang , Jia-shou Wua, Wei-zhong Gong, Yue Cheng, Jing Xiang,Qi-Zhong Zhou, Synthesis of 2-heterocyclic substituted pyrrolidines by coppercatalyzed domino three-component decarboxylative coupling and cyclization reactions, Tetrahedron Letters 2015, 56, 2720–2723.

27. J. Xiang, W.-L. Man, J.-F. Guo, S.-M.Yiu, G.-H. Lee, S.-M. Peng,G.-C. Xu, S. Gao and T.-C. Lau,A novel tricyanoruthenium(III) building block for the construction of bimetallic coordination polymers, Chem. Commun.,2010, 46, 6102-6104.

28. J. Xiang, L.-H. Jia, W.-L. Man, K. Qian, S.-M.Yiu, G.-H. Lee,S.-M. Peng,S. Gao and T.-C.Lau,Novel heterobimetallic ruthenium(III)–cobalt(II) compounds constructedfrom trans-[Ru ^III(Q) ₂(CN) ₂] ^– (Q = 8-quinolinolato): synthesis,structures and magnetic properties, Chem. Commun.,2011, 47, 8694–8696.

29. J. Xiang, W.-L. Man, S.-M.Yiu, S.-M. Peng, and T.-C. Lau, Reaction of an Osmium(VI) Nitrido Complex with Cyanide: Formation andReactivity of an Osmium(III) Hydrogen Cyanamide Complex, Chem. Eur. J.,2011, 17, 13044-13051.

30. J. Xiang, L. T.-L. Lo, C.-F. Leung, S.-M.Yiu, C.-C. Ko, and T.-C. Lau, Synthesis, Structures, and Photophysical Properties of Ruthenium(II)Quinolinolato Complexes Organometallics, 2012, 31, 7101−7108.

31. J. Xiang, L.-H. Jia, W.-L. Man, K. Qian, G.-H. Lee, S.-M. Peng, S.-M.Yiu,S. Gao and T.-C. Lau, A novel triazidoruthenium(III) building block for the construction of polynuclear compounds, Dalton Trans.2012, 41, 5794-5798.

32. J. Xiang, L.-H. Jia, B.-W. Wang, S.-M.Yiu, S.-M. Peng,W.-Y. Wong, S. Gao and T.-C. Lau, The synthesis, structures and magnetic properties of polynuclear Ru ^III-3d (3d = Mn ^II/III, Ni ^II, Cu ^II) compounds based on [Ru ^III(Q) ₂(CN) ₂] ^–, Dalton Trans.2013, 42, 3876-3887.

33. C.-F. leung, S.-M. Yiu, J. Xiang and T.-C. Lau, Addition of [CH(CN) ₂] ^–and [TCNE] ^•–to Ru ^VI≡N bearing 8-quinolinolato ligands, Chem. Commun., 2010, 46,7575-7577.

34. C.-F. Leung, S.-M. Ng,J. Xiang, W.-Y. Wong, Michael H.-W. Lam,C.-C. Ko, and T.-C. Lau,Synthesis and Photophysical Properties of Ruthenium(II) IsocyanideComplexes Containing 8-Quinolinolate Ligands, Organometallics, 2009, 28, 5709–5714.

35. H.-K.Kwong, W.-L. Man, J. Xiang, W.-T. Wong, and T.-C. Lau, Reaction of a (Salen)ruthenium(VI) Nitrido Complex with Isocyanide, Inorg. Chem. 2009, 48, 3080-3086.

36. W.-L. Man, H.-K.Kwong, William W. Y. Lam, J. Xiang, T.-W. Wong, W.-H. Lam,W.-T. Wong, S.-M. Peng, and T.-C. Lau,General Synthesis of (Salen)ruthenium(III) Complexes via N···NCoupling of (Salen)ruthenium(VI) Nitrides” Inorg. Chem. 2008, 47, 5936-5944.